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浙师大化学与生命科学学院导师介绍:胡庚申


  姓名:胡庚申 
  性别:男 
  职称:教授 
  所在学院:化学与生命科学学院 

  个人简介
  胡庚申,出生于陕西省韩城市,2001年毕业于浙江大学化学系,获得学士学位。
  2008年毕业于中国科学院大连化学物理研究所,获得博士学位,从事小分子与金属纳米粒子相互作用的表面增强拉曼光谱研究,导师为李灿研究员/院士。2008年至2010年在美国University of South Carolina从事博士后研究工作,主要从事有机胺溶液捕捉和释放CO2的研究工作,合作导师为Christopher T. Williams教授。2010年12月加入浙江师范大学物理化学研究所从事科学研究工作,主要从事小分子在催化剂表面吸附、脱附、溢流、共吸附和反应等行为的原位动态振动光谱表征。

  研究兴趣
  原位红外光谱、原位拉曼光谱、多相催化、表面化学、CO2捕捉、环境催化
  In-situ (Operando) IR and Raman, heterogeneous catalysis, surface science, CO2 capture
 
  代表性学术论文:
  [1] Hu, G. S;Gao, H. S;Williams, C. T, The CO desorption ability on Pt enhanced by Al2O3: An in-situ ATR-IR investigation. J. Phys. Chem. C 2012, 116, 6247-6250.
  [2] Hu, G. S;Zhu, L;Jia, A. M;Hu, X;Xie, G. Q;Lu, J. Q;Luo, M. F, In-situ real-time DRIFTS Study of Hydrogen Adsorption and desorption on Ir/SiO2 catalyst. Appl. Spectrosc. 2012, 66, in press.
  [3] Hu, G. S;Zhu, L;Jia, A. M;Hu, X;Xie, G. Q;Lu, J. Q;Luo, M. F, CO2 Adsorption and Desorption on MgO/Al2O3: An In Situ Diffuse Reflection Infrared Fourier Transform Spectroscopy (DRIFTS) Study. Appl. Spectrosc. 2012, 66, 122-127.
  [4] Jia, A.-P;Hu, G. S;Meng, L;Lu, J.-Q;Luo, M.-F, CO oxidation over CuO/Ce1-xCuxO2-δ and Ce1-xCuxO2-δ catalysts: Synergetic effects of CuO species and kinetic study. J. Catal. 2012, Accepted.
  [5] Zhu, L;Hu, G. S;Lu, J. Q;Xie, G. Q;Chen, P;Luo, M. F, Effects of Ir content on selective hydrogenation of crotonaldehyde over Ir/ZrO2 catalysts. Catal. Commun. 2012, 21, 5-8.
  [6] Li, L;Hu, G. S;Chen, F;Luo, M. F, Defect Sites in the Ce1-xGdxO2-δ Solid Solutions by Raman Spectroscopy. Chin. J. Inorg. Chem. 2012, 28, 20-24.
  [7] Li, L;Hu, G. S;Lu, J. Q;Luo, M. F, Review in Oxygen Vacancies of CeO2-doped solid solutions by Characterization of Raman Spectra. Acta Phys. -Chim. Sin. 2012, In press.
  [8] Dai, W;Liu, Y;Su, W;Hu, G. S;Hu, X, Preparation and CO2 adsorption of high surface area activated carbon from KOH activation of Foshou residue for CO2 sorption. Adsorption 2012, In press.
  [9] Wu, Y;Hu, G. S;Xie, Y;Guo, M;Luo, M, Solid State Reaction of MoO3-CeO2 Complex Oxide Studied by Raman Spectroscopy. Solid State Sci. 2011, 13, 2096-2099.
  [10] Hu, G. S;Han, D. F;Jia, G. Q;Chen, T;Feng, Z. C;Li, C, Coadsorption of trimethyl phosphine and thiocyanate on colloidal silver: a SERS study combined with theoretical calculations. J. Raman Spectrosc. 2009, 40, 387-393.
  [11] Hu, G. S;Feng, Z. H;Han, D. F;Li, J;Jia, G. Q;Shi, J. Y;Li, C, Charge transfer between triphenyl phosphine and colloidal silver: A SERS study combined with DFT calculations. J. Phys. Chem. C 2007, 111, 8632-8637.
  [12] Hu, G. S;Feng, Z. C;Li, J;Jia, G. Q;Han, D. F;Liu, Z. M;Li, C, Adsorption of ethanediamine on colloidal silver: A surface-enhanced raman spectroscopy study combined with density functional theory calculations. J. Phys. Chem. C 2007, 111, 11267-11274.
  [13] Hu, G. S;Feng, Z. C;Li, J;Han, D. F;Jia, G. Q;Li, C, Adsorption of Diphenyl Ethanediamine (DPEDA) on Colloidal Silver Surface: A SERS Study. Chinese Journal of Light Scattering 2008, 20, 105-107.
  [14] Lei, Z. B;Xiao, Y;Dang, L. Q;You, W. S;Hu, G. S;Zhang, J, Nickel-catalyzed fabrication of SiO2, TiO2/graphitized carbon, and the resultant graphitized carbon with periodically macroporous structure. Chem. Mater. 2007, 19, 477-484.
  [15] Han, D. F;Li, X. H;Zhang, H. D;Liu, Z. M;Hu, G. S;Li, C, Asymmetric hydroformylation of olefins catalyzed by rhodium nanoparticles chirally stabilized with (R)-BINAP ligand. J. Mol. Catal. A: Chem. 2008, 283, 15-22.

  申请专利
  [1] 胡庚申; 罗孟飞; 贾爱平. 一种原位红外光谱池(一种原位双通道透射红外光谱池), 申请号:201110456379.3.
  [2] 胡庚申; 罗孟飞; 贾爱平; 冯星星. 一种用于研究气液固三相界面的原位红外光谱池, 申请号:201210031440.4.
  [3] 胡庚申; 罗孟飞; 贾爱平; 冯星星. 一种用于气固界面或液固界面研究的原位红外光谱池, 申请号:201210031627.4.
  [4] 罗孟飞; 彭小波; 谢冠群; 胡庚申. 一种2, 3, 3, 3-四氟丙烯的制备方法, 申请号:201110256154.3.
  [5] 罗孟飞; 朱琳; 陈萍; 谢冠群; 胡庚申. 用于气相巴豆醛选择性加氢制备巴豆醇的催化剂及其制备方法, 申请号:201110116987.X.

  投稿中或即将投稿的学术论文
  [1] Hu, G. S, Hydrogen Adsorption and Oxidation on Pt film: An in-situ ATR-IR Study. to be submitted. 2012.
  [2] Hu, G. S, Coadsorption of H2 and CO on Pt film: An in-situ ATR-IR Study Combined with Density Functional Theoretical Calculations. to be submitted. 2012.
  [3] Hu, G. S, The Application of Curve-fitting Analysis to Quantitative Analysis of IR and Raman Spectra. to be submitted. 2012.
  [4] Hu, G. S, The influence of Pt film thickness on CO frequency: An ATR-IR Study Combined with DFT Calculations. To be submitted 2012.
  [5] Hu, G. S, The adsorption of Benzylamine on Ag Nanoparticles: A SERS Study Combined with DFT Calculations. to be submitted. 2012.
  [6] Hu, G. S, Surface-enhanced Raman Scattering Spectroscopy Study the adsorption of Quinoline and Cinchonidine on Ag Nanoparticles. to be submitted. 2012.
  [7] Zhu, L;Lu, J.-Q;Chen, P;Hong, X;Xie, G.-Q;Hu, G. S;Luo, M. F, A comparative study on Pt/CeO2 and Pt/ZrO2 catalysts for crotonaldehyde hydrogenation. J. Mol. Catal. A: Chem. 2012, Revision under review.

  2011年以来参加学术会议
  [1] 胡庚申; 鲁继青; 罗孟飞. 氢在Pt膜上吸附与氧化的原位ATR-IR研究,第13届全国青年催化会议,昆明,2011年7月. 口头报告
  [2] 胡庚申; 朱琳; 贾爱平; 鲁继青; 罗孟飞. CO2在MgO/Al2O3表面吸附和脱附的原位动态红外光谱研究,第13届全国青年催化会议,厦门,2011年11月. 口头报告
  
  设计和加工的实验装置
  (1)用于气固界面或液固界面的原位衰减全反射红外光谱池(申请号:201210031627.4.)
  (2)用于研究气液固三相界面的原位红外光谱池 (申请号:201210031440.4)
  (3)一种原位双通道透射红外光谱池(申请号:201110456379.3.)

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