浙师大化学与生命科学学院导师介绍:钱兆生
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姓名:钱兆生 性别:男 职称:副教授 所在学院:化学与生命科学学院
姓名:钱兆生
性别:男
职称:副教授
所在学院:化学与生命科学学院
个人简介:
钱兆生,博士,副教授,硕士生导师,分析学科主任。
2009.6月南京大学化学化工学院化学专业获理学博士学位,博士论文曾获2010年度南京大学和江苏省优秀博士学位论文,获2011年度全国优秀博士学位论文提名论文。2009.8起在浙江师范大学分析化学学科开展分析化学教学工作和相关科研工作。
目前从事于碳纳米材料的光致发光性能及其传感应用研究、水溶液中大无机离子团簇的结构及其性质研究和基于小分子有机化合物的分子开关的设计与合成。
已在JACS、ChemComm、J. Mater. Chem.、GCA、ES&T等国际著名学术期刊上发表二十余篇论文; 曾被邀为JACS、Talanta等刊物的审稿人。
主要研究方向
(1)碳纳米材料的光致发光性能及其传感应用研究
(2)水溶液中大无机离子团簇的结构及其性质研究
(3)基于小分子有机化合物的分子开关的设计与合成
科研项目
(1)铝形态水交换反应在碳基纳米管作用下的动力学研究 国家自然科学基金青年科学基金 2011 -2013 主持
(2)多层薄膜型拉曼器件的设计、构建及远程调控 国家自然科学基金面上项目 2012 – 2016 参与
发表学术论文
(1)Zhaosheng Qian*, Congcong chen, Jianrong Chen, Lichun Kong, Chen Wang, Jin Zhou, Hui Feng. Unusual visible luminescence of aluminium polyoxocations in aqueous solution. Chem. Commun., 2011, 47, 12652-12654.
(2)Zhaosheng Qian*, Jin Zhou, Jianrong Chen, Chen Wang, Congcong Chen, Hui Feng. Nanosized N-doped graphene oxide with visible fluorescence in water for metal ions sensing. J. Mater. Chem. 2011, 21, 17635-17637.
(3)Jinjin Chen, Keming Fang, Yuqing Miao, Zhaosheng Qian, Jianrong Chen. Study on adsorption of Co(II)and Ni(II)onto mesoporous Ti-containing MCM-48. J. Nanosci. Nanotech., 2011, 11, 6796-6803.
(4)Zhaosheng Qian*, Chen Wang, Hui Feng, Congcong Chen, Jin Zhou, Jianrong Chen. Well dispersed single-walled carbon nanotubes with strong visible fluorescence in water for metal ions sensing. Chem. Commun. 2011, 47, 7167-7169.
(5)Xiaoyan Jin, Wenjing Yang, Zhaosheng Qian, Yingjie Wang, Shuping Bi. DFT study on the interaction between monomeric aluminium and chloride ion in aqueous solution. Dalton Trans. 2011, 40, 5052-5058.
(6)Hui Feng, Zhaosheng Qian*, Chen Wang, Congcong Chen, Jianrong Chen. Tuning the energy barrier of water exchange reactions on Al(III)by interaction with the single-walled carbon nanotubes. Dalton Trans. 2011, 40 (16), 4183 - 4189.
(7)Hui Feng, Zhaosheng Qian*, Chen Wang, Congcong Chen, Jianrong Chen. Theoretical investigation of formation mechanism of bipyridyl molecule on Ni(111)surface: implication for synthesis of N-doped graphene from pyridine. Phys. Chem. Chem. Phys. 2011, 13, 6053.
(8)Xiaoyan Jin, Zhaosheng Qian, Bangmei Lu, Shuping Bi. DFT study on the mechanism for the substitution of F- into Al(III)complexes in aqueous solution. Dalton Trans., 2011, 40, 567-572.
(9)Xiaoyan Jin, Zhaosheng Qian, Bangmei Lu, Wenjing Yang, Shuping Bi. Density Functional Theory Study on Aqueous Aluminum-Fluoride Complexes: Exploration of the Intrinsic Relationship between Water-Exchange Rate Constants and Structural Parameters for Monomer Aluminum Complexes. Environ. Sci. Technol., 2011, 45, 288-293.
(10)Xiaoyan Jin, Zhaosheng Qian, Bangmei Lu, Shuping Bi. DFT study on the mechanism for the subsitution of F- into Al complexes in aqueous solution. Dalton Trans., 2010, 40, 567-572.
(11)Zhaosheng Qian, Hui Feng, Chen Wang, Jianrong Chen. Theoretical investigation of the dissociative interchange (Id)mechanism for water exchange on magnesium(II)in aqueous solution. Inorg. Chem. Acta, 2010, 363, 3627.
(12)Yang, W. J.; Qian, Z. S.; Lu, B. M.; Zhang, J.; Bi. S. P. Density functional theory study and kinetic analysis of the formation mechanism of Al30O8(OH)56(H2O)2618+ (Al30)in aqueous solution. Geochim. Cosmochim. Acta 2010, 74, 1220-1229.
(13)Qian, Z. S.; Feng, H.; Yang, W. J.; Jin, X. Y.; Wang, Y. J.; Bi, S. P. Density functional studies of the structural characteristics, 27Al NMR chemical shifts and water-exchange reactions of Al30O8(OH)24(H2O)2618+ (Al30)in aqueous solution. Geochim. Cosmochim. Acta 2010, 74, 1230-1237.
(14)Qian, Z. S.; Feng, H.; Zhang, Z. J.; Yang, W. J.; Wang, Y. J.; Bi, S. P. Theoretical Exploration of water exchange mechanism of the polyoxocation GaO4Al12(OH)24(H2O)127+ in aqueous solution. Geochim. Cosmochim. Acta 2009, 73, 1588-1596.
(15)Qian, Z. S.; Feng, H.; Zhang, Z. J.; Yang, W. J.; Jin, J.; Miao, Q.; He, L. N.; Bi, S. P. Theoretical investigation on the dimerization of the deprontonated aquo ion of Al( III)in water. Dalton Trans. 2009, 521-529.
(16)Qian, Z. S.; Feng, H.; Yang, W. J.; Zhang, Z. J.; Wang, Y. J.; Bi, S. P. Theoretical investigation of dehydration of aquated Al(OH)2+ species in aqueous solution. Dalton Trans. 2009, 1554-1558.
(17)Qian, Z. S.; Feng, H.; He, L. N.; Yang, W. J.; Bi, S. P. Assessment of the accuracy of theoretical methods for calculating 27Al nuclear magnetic resonance shielding tensor of aquated aluminum species. J. Phys. Chem. A 2009, 113, 5138-5143.
(18)Qian, Z. S.; Feng, H.; Yang, W. J.; Jin, X. Y.; Bi, S. P. Density functional study of the water exchange reaction of the polyoxocation GeO4Al12(OH)24(H2O)128+ (K-GeAl12)in aqueous solution. Dalton Trans. 2009, 8013-8017.
(19)Qian, Z. S.; Feng, H.; Jin, X. Y.; Yang, W. J.; Wang, Y. J.; Bi, S. P. Density functional investigation of the water exchange reaction on the gibbsite surface. Environ. Sci. Technol. 2009, 43, 9281-9286.
(20)Yang, W. J.; Qian, Z. S.; Miao, Q.; Wang, Y. J.; Bi. S. P. Density functional theory study of the aluminium(III)hydrolysis in aqueous solution. Phys. Chem. Chem. Phys. 2009, 11, 2396-2401.
(21)Qian, Z. S.; Feng, H.; Yang, W. J.; Bi, S. P. Theoretical investigation of water exchange on the nanometer-sized polyoxocation AlO4Al12(OH)24(H2O)127+ (Keggin-Al13)in aqueous solution. J. Am. Chem. Soc. 2008, 130, 14402-14403.
(22)Qian, Z. S.; Feng, H.; Yang, W. J.; Miao, Q.; He, L. N.; Bi, S. P. Supermolecule density functional calculations on the water exchange of aquated Al(III)species in aqueous solution. Chem. Commun. 2008, 3930-3932.
(23)钱兆生, 周传健, 李根, 曹玲华. 糖基修饰的氨基酸类化合物的合成. 有机化学, 2008, 28, 467-471.
(24)田添, 曹玲华, 钱兆生. N-糖基-Nˊ-酰氨基硫脲及其环合产物的合成. 有机化学, 2007, 27, 744-748.
(25)钱兆生, 周传健, 曹玲华. 糖基异硫氰酸酯的合成及其应用. 化学进展, 2006, 18, 429-439.
(26)李根, 钱兆生, 曹玲华. 半乳糖伯羟基氧化及其衍生物的合成. 应用化学, 2005, 22, 1182-1186。
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