苏州大学材料与化学化工学部导师介绍:徐凡
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姓名:徐凡 职称:教授、硕士生导师 部门:有机化学研究所 联系方式: Tel: 86-512-6588
姓名:徐凡
职称:教授、硕士生导师
部门:有机化学研究所
联系方式:
Tel: 86-512-65880331 (o), 65880980 (Lab)
Fax: 86-512-65880305 (o)
Email: xufan@suda.edu.cn
学历及学术经历:
1990年苏州大学本科毕业,1993年获苏州大学有机化学专业硕士学位,2004年获苏州大学有机化学专业博士学位。2003年受聘为苏州大学材化部有 机化学专业硕士生导师,2009年任教授。近5年来,主持国家自然科学基金项目一项、江苏省自然科学基金项目一项及江苏省有机合成重点实验室开放课题两 项;作为主要参与者参加多项国家自然科学基金和省部级基金项目。在国内外核心化学期刊上发表论文60余篇。
研究领域:
新型稀土催化剂的设计、合成与应用;选择性有机合成方法。
代表性论文:
1. Samarium Diiodide Promoted Synthesis of N,N’-Disubstituted Amidines, F. Xu, J. Sun, Q. Shen, Tetrahedron Lett. 2002, 43, 1867.
2. One-pot Synthesis of α-Amino Phospho- nates Using Samarium Diiodide as a Catalyst Precursor, F. Xu, Y. Luo, Q. Shen, Eur. J. Org. Chem. 2003, 24, 4728.
3. Efficient Synthesis of 1,5-Benzodiazepine Derivatives by Ytterbium Trichloride-Catalyzed Condensation of o-Phenylenediamine and Ketones, J. Wu, F. Xu*, Z. Zhou, Q. Shen, Synth. Commun. 2006, 36, 457.
4. Facile One-pot Synthesis of α-Amino Phosphonates Using Lanthanide Chloride as Catalyst, F. Xu, Y. Luo, J. Wu, Q. Shen, H. Chen, Heteroatom Chem. 2006, 17, 389.
5. Stereoselective Synthesis of Pyrano[3,2-c]- and Furano[3,2-c]Quinolines:Samarium Diiodide Catalyzed One-Pot Aza–Diels–Alder Reaction, Z. Zhou, F. Xu*, X. Han, J. Zhou, Q. Shen, Eur. J. Org. Chem. 2007,5265.
6. Efficient Synthesis of Pyrimidinone Derivatives by Ytterbium Chloride Catalyzed Biginelli-type Reaction under Solvent-free Conditions, H. Zhang, Z. Zhou, Z. Yao, F. Xu*, Q. Shen, Tetrahedron Lett.2009, 50, 1622.
7. A Facile Route to 1,5-Benzodiazepine-2-ylphosphonates via Ytterbium Chloride-Catalyzed Three-Component Reaction, X. Ji, L. Cai, Z. Yao, F. Xu*, Q. Shen, Heteroatom Chem. 2010, 21, 89.
8. Stereoselective : Gadolinium Chloride Catalyzed One-pot Aza-Diels-Alder Reactions, Y. Yu, J. Zhou, Z. Yao, F. Xu*, Q. Shen, Heteroatom Chem. 2010, 21, 351.
9. Lanthanide Amides [(Me3Si)2N]3Ln(m-Cl)Li(THF)3 CatalyzedHydrophosphonylation of Aryl Aldehydes, Q. Wu, J. Zhou, Z. Yao, F. Xu*, Q. Shen, J. Org. Chem. 2010, 75, 7498.
10. Controllable Stereoselective Synthesis of Pyrano[3,2-c]quinolines by Lanthanide Halides Catalyzed Aza-Diels-Alder Reaction, L. Yao, F. Xu*, Q. Shen, Chinese Science Bulletin 2010, 55, 4108.
11.Acylation of Nitriles to β-Ketonitriles Catalyzed by Heterometal Alkoxide Cluster of Neodymium and Sodium NdNa8(OtBu)10(OH), H. Liu, L. Li, H. Sheng, X. Zhu, F. Xu*, Q. Shen, Chinese Science Bulletin, 2011, 56, 1357.
12. Activation of Carbodiimide and Transformation with Amine to Guanidinate Group by Ln(OAr)3(THF)2 (Ln: Lanthanide and Yttrium) and Ln(OAr)3(THF)2 as a Novel Precatalyst for Addition of Amines to Carbodiimides: Influence of Aryloxide Group, Y. Cao, Z. Du, W. Li, J. Li, Y. Zhang, F. Xu*, Q. Shen*, Inorganic Chemistry 2011, 50, 3729.
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