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河南大学化学化工学院导师介绍:赵俊伟


  姓名:赵俊伟(博士)
  系别:化学系
  职称:副教授
  院内行政职务:
  电话:************
  传真:************
  邮箱:zhaojunwei@henu.edu.cn

  个人简介
  主要教育经历:
  1998.9-2002.7 河南大学 化学 本科
  2002.9-2005.7 河南大学 无机化学 硕士
  2005.9-2008.7 中国科学院福建物质结构研究所 无机化学 博士
  2010.1-2012.6 河南大学化学博士后流动站 无机化学 博士后
  主要工作经历:
  2008.8-2010.10 河南大学化学化工学院 讲师
  2010.10至今 河南大学化学化工学院 副教授
  2009.7至今 河南大学化学化工学院 硕士生导师

  研究方向及讲授课程
  研究方向:
  (1) 新型多金属氧酸盐的合成与制备化学及其发光、电学、磁性、铁电等物理化学性能研究
  (2) 手性分子基功能材料的制备及手性识别、手性催化、铁电压电及非线性光学研究
  相关研究成果在Chem.Commun.,Chem.Eur.J.,Inorg.Chem.,Cryst.Growth Des.,Dalton Trans.,CrystEngComm,Eur.J.Inorg.Chem.,J.Solid State Chem.等国外知名杂志上发表学术论文70余篇。
  讲授课程:
  主要担任本科生《无机化学》、《无机化学实验》、《无机及分析化学实验》和研究生《单晶X-射线结构分析》、《磁化学基础》等课程教学,参编《无机化学实验》和《无机及分析化学》两部教材。荣获河南大学教学优秀奖和河南大学教学质量竞赛二等奖。

  研究成果
  论文:
  1.J.W.Zhao,* D.Y.Shi,L.J.Chen,Y.Z.Li,P.T.Ma,J.P.Wang,J.Y.Niu,* Novel polyoxometalate hybrids containing copper-lanthanide heterometallic germanotungstate / lanthanide-germanotungstate fragments,Dalton Trans.2012,accepted.
  2.J.W.Zhao,* D.Y.Shi,L.J.Chen,X.M.Cai,Z.Q.Wang,P.T.Ma,J.P.Wang,J.Y.Niu,* Two organic–inorganic hybrid 1-D and 3-D polyoxotungstates constructed from hexa-CuII substituted sandwich-type arsenotungstate units,CrystEngComm,2012,14,2797-2806.
  3.D.Y.Shi,J.W.Zhao,* L.J.Chen,P.T.Ma,J.P.Wang,J.Y.Niu,* Four types of 1D or 2D organic–inorganic hybrids assembled by arsenotungstates and CuII–LnIII/IV heterometals,CrystEngComm,2012,14,3108-3119.
  4.D.Y,Shi,S.S.Shang,L.J.Chen,X.M.Cai,X.Y.Wang,J.W.Zhao,∗ Three novel 2D organic–inorganic hybrid CuII–LnIII heterometallic arsenotungstates,Synth.Met.2012,1030–1036.
  5.W.J.Niu,D.Y.Shi,J.W.Zhao,* X.M.Cai,L.J.Chen,An organic – inorganic hybrid hexa-nickel substituted sandwich-type germanotungstate [enH2]2[Ni(en)2]2 {[Ni6(en)2(H2O)2][B-α-GeW9O34]2}•14H2O,Inorg.Chem.Commun.2012,17,79–83.
  6.D.Y.Shi,S.Z.Li,J.W.Zhao,* W.J.Niu,S.S.Shang,Y.Z.Li,P.T.Ma,L.J.Chen,Synthesis,structure and properties of a metal–organic complex built up from ferrous sulfate chains and 2,2'-bipyridyl-5,5'-dicarboxylic acid ligands,Inorg.Chem.Commun.2012,20,277–281.
  7.J.Luo,C.L.Leng,L.J.Chen,J.Yuan,H.Y.Li,J.W.Zhao,* Three 3D organic–inorganic hybrid heterometallic polyoxotungstates assembled from 1:2-type [Ln(α-SiW11O39)2]13– silicotungstates and [Cu(dap)2]2+ linkers,Synth.Met.2012,accepted.
  8.D.Y.Shi,Z.Q.Wang,J.J.Xing,Y.Y.Li,J.Luo,L.J.Chen,J.W.Zhao,* A 2-D organic–inorganic hybrid copper-yttrium heterometallic monovacant Keggin phosphotungstate derivative: [Cu(dap)2]5.5[Y(α-PW11O39)2]•4H2O,Synth.React.Inorg.Met.-Org.Nano- Met.Chem.2012,42,30–36.
  9.J.W.Zhao,* D.Y.Shi,L.J.Chen,P.T.Ma,J.P.Wang,J.Y.Niu,Two 1-D multi-nickel substituted arsenotungstate aggregates,CrystEngComm,2011,13,3462–3469.
  10.L.J.Chen,D.Y.Shi,J.W.Zhao,* Y.L.Wang,P.T.Ma,J.P.Wang,J.Y.Niu,Three transition-metal substituted polyoxotungstates containing Keggin fragments: from trimer,one-dimensional chain to two-dimensional sheet,Cryst.Growth Des.2011,11,1913–1923.
  11.J.W.Zhao,* Q.X.Han,D.Y.Shi,L.J.Chen,P.T.Ma,J.P.Wang,J.Y.Niu,Synthesis,structure and magnetism of a S-shaped multi-iron substituted arsenotungstate containing a trivacant Keggin [B-α-AsVW9O34]9- and a hexavacant Keggin [α-AsVW6O26]11- fragments,J.Solid State Chem.2011,184,12756–2761.
  12.D.Y.Shi,L.J.Chen,J.W.Zhao,* Y.Wang,P.T.Ma,J.Y.Niu,Two novel 2D organic–inorganic hybrid lacunary Keggin phosphotungstate 3d–4f heterometallic derivatives: [Cu(en)2]2H6[Ce(α-PW11O39)2]•8H2O and [Cu(dap)2(H2O)][Cu(dap)2]4.5 [Dy(α-PW11O39)2]•4 H2O,Inorg.Chem.Commun.2011,14,324–329.
  13.Y.Liu,D.Y.Shi,J.W.Zhao,* L.J.Chen,Z.Q.Wang,P.T.Ma,J.Y.Niu,An organic–inorganic hybrid dimeric arsenotungstate [enH2]4{[Cu(en)2][(A-β-H2As W9O34)Cu(en)2]2}•8H2O established by two trivacant Keggin [A-β-AsW9O34]9− fragments in the opposite orientation,Inorg.Chem.Commun.2011,14,1178–1182.
  14.Q.X.Han,P.T.Ma,J.W.Zhao,* J.P.Wang,J.Y.Niu,A novel 1D tungstoarsenate with mixed organic ligands assembled by hexa-Cu sandwiched Keggin units and dinuclear copper-oxalate complexes,Inorg.Chem.Commun.2011,14,767–770.
  15.X.Zhu,J.W.Zhao,B.L.Li,* Y.Song,Y.M.Zhang,Y.Zhang,A two-dimensional metal-organic framework based on a ferromagnetic pentanuclear copper( II ),Inorg.Chem.2010,49,1266–1270.
  16.J.W.Zhao,* D.Y.Shi,H.L.Cheng,L.J.Chen,P.T.Ma,J.Y.Niu,One-pot syntheses,structures and properties of two novel 1-D copper complexes: [CuII2(Hbpdc)2Cl2]2•2H2O and CuI(H2bpdc)Cl(H2bpdc = 2,2'-bipyridyl-5,5'- dicarboxylic acid),Inorg.Chem.Commun.2010,13,822–827.
  17.L.J.Chen,J.W.Zhao,* P.T.Ma,Q.X.Han,J.P.Wang,J.Y.Niu,An organic-inorganic hybrid nickel-substituted arsenotungstate consisting of three types of polyoxotungstate units,Inorg.Chem.Commun.2010,13,50–53.
  18.J.W.Zhao,S.T.Zheng,Z.H.Li,G.Y.Yang*,Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: first 65•8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates,Dalton Trans.2009,1300–1306.
  19.S.Z.Li,J.W.Zhao,P.T.Ma,J.Du,J.Y.Niu,* J.P.Wang,Rare sandwich-type polyoxomolybdates constructed from di-/tetra-nuclear transition-metal clusters and trivacant Keggin germanomolybdate fragments,Inorg.Chem.2009,48,9819–9830.
  20.B.Li,J.W.Zhao,S.T.Zheng,G.Y.Yang,* Combination chemistry of hexa-copper- substituted polyoxometalates driven by the CuII-polyhedra distortion: from tetramer,1D chain to 3D framework,Inorg.Chem.2009,48,8294–8303.
  21.J.P.Wang,J.W.Zhao,P.T.Ma,J.C.Ma,L.P.Yang,Y.Bai,M.X.Li,J.Y.Niu,* A novel type of heteropolyoxoanion precursors {[Ca(H2O)]6[P4M6O34]2}12– (M = WVI,MoVI) constructed by two [P4M6O34]12– subunits via a rare hexa-calcium cluster,Chem.Commun.2009,2362– 2364.
  22.J.W.Zhao,Y.P.Song,P.T.Ma,J.P.Wang,J.Y.Niu*,Hydrothermal syntheses,crystal structures and properties of 0-D,1-D and 2-D organic-inorganic hybrid borotungstates constructed from Keggin-type heteropolyanion [α-BW12O40]5- and transition-metal complexes,J.Solid State Chem.2009,182,1798–1805 J.Solid State Chem.2009,182,1798–1805.
  23.J.W.Zhao,J.L.Li,P.T.Ma,J.P.Wang,J.Y.Niu*,Synthesis,structure and magnetic property of the first 2-D organic-inorganic hybrid sandwich-type polyoxotungstate containing O-donor organic ligands,Inorg.Chem.Commun.2009,12,450–453.
  24.J.W.Zhao,* Q.X.Han,P.T.Ma,L.J.Chen,J.P.Wang,J.Y.Niu,A CdSO4-like 3-D framework constructed from mono-sodium substituted Keggin arsenotungstates and copper(II)-ethylenediamine complexes,Inorg.Chem.Commun.2009,12,707–710.
  25.J.W.Zhao,J.P.Liu,J.P.Wang,J.Y.Niu*,Synthesis and crystal structure of the first two-dimensional inorganic / organic composite solid of iron(III) molybdate,Chem.Lett.2009,38,474–475.
  26.J.W.Zhao,P.T.Ma,J.P.Wang,J.Y.Niu*,Synthesis and structural characterization of a novel three-dimensional molybdenum-oxygen framework constructed from Mo3O9 units,Chem.Lett.2009,38,694–695.
  27.J.W.Zhao,C.M.Wang,J.Zhang,S.T.Zheng,G.Y.Yang*,Combination of lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: IX.A series of novel polyoxotungstates sandwiched by octa-copper clusters,Chem.Eur.J.2008,14,9923–9239.
  28.J.W.Zhao,J.Zhang,S.T.Zheng,G.Y.Yang*,Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster,Chem.Commun.2008,570–572.
  29.J.W.Zhao,J.Zhang,Y.Song,S.T.Zheng,G.Y.Yang*,Two hexanickel-substituted Keggin-type germanotungstates,Eur.J.Inorg.Chem.2008,3809–3819.
  30.J.W.Zhao,S.T.Zheng,G.Y.Yang*,0-D and 1-D inorganic–organic composite polyoxotungstates constructed from in-situ generated monocopperII-substituted Keggin polyoxoanions and copperII-organoamine complexes,J.Solid State Chem.2008,181,2205–2216.
  31.J.W.Zhao,S.T.Zheng,W.Liu,G.Y.Yang,* Hydrothermal synthesis and structural characterization of two 1-D and 2-D Dawson-based phosphotungstates,J.Solid State Chem.2008,181,637–645.
  32.J.W.Zhao,J.H.Peng,J.Zhang,S.T.Zheng,G.Y.Yang*,A combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions.Part II: From double cluster,dimer,and tetramer to three-dimensional frameworks,Chem.Eur.J.2007,13,10030–10045.
  33.J.W.Zhao,J.Zhang,S.T.Zheng,G.Y.Yang*,Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions.5.A novel tetrameric cluster of [{FeIIFeIII12(μ3-OH)12(μ4-PO4)4}(B-α- PW9O34)4]22-,Inorg.Chem.2007,46,10944–10946.
  34.J.W.Zhao,B.Li,S.T.Zheng,G.Y.Yang*,Two-dimensional extended (4,4)-topological network constructed from tetra-NiII-substituted sandwich-type Keggin polyoxometalate building blocks and NiII-organic cation bridges,Cryst.Growth Des.2007,7,2658–2664.
  35.J.W.Zhao,S.T.Zheng,G.Y.Yang*,Hydrothermal synthesis and structural characterization of three inorganic–organic composite sandwich-type phosphotungstates,J.Solid State Chem.2007,180,3317–3324.
  著作:
  1.《无机化学实验》,ISBN 978-7-122-08934-2,化学工业出版社,2010年8月,参编约6万字。
  2.《无机及分析化学》,ISBN 978-7-308-09015-3,浙江大学出版社,2011年9月,参编约7万字。
  课题:
  1.有机-无机杂化钨氧簇基材料的制备、铁电及磁性研究(21101055),1.国家自然科学基金,主持。
  2.有机-无机杂化多钨氧酸盐基3d-4f异金属衍生材料的制备、铁电及磁性研究(201104392),中国博士后特别资助,主持。
  3.无机-有机杂化钨-氧簇基铁电和磁性材料的制备与性能研究(20120013),结构化学国家重点实验室开放基金,主持。
  4.多金属氧酸盐基3d-4f金属衍生物的合成及荧光磁性研究(20100470996),中国博士后科学基金,主持。
  5.稀土簇与缺位多金属氧酸盐簇的组装化学及相关性能研究(************),河南省科技厅自然科学基金,主持。
  6.有机无机复合钨氧簇基材料的设计及铁电磁性能研究,河南省科技厅自然科学基金(122300410106),主持。
  7.有机-无机杂化的过渡金属取代多钨氧酸盐的制备和磁性研究(2010B150006),河南省教育厅自然科学基金,主持。
  8.稀土簇与缺位多金属氧酸盐簇的组装化学及相关性能研究(2008YBZR010),河南大学自然科学基金,主持。
  9.多金属氧酸盐基3d-4f异金属衍生物的合成及荧光磁性研究,2012年河南大学大学生创新性实验计划项目,指导。
  10.多金属氧酸盐基的稀土簇荧光材料研究,2009年河南大学大学生创新性实验计划项目,指导。

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