安徽师范大学化学与材料科学学院导师介绍：周双六

　　姓名：周双六
　　性别：男
　　出生年月：
　　职称：副教授
　　学院：化学与材料科学学院
　　研究方向：

　　所受教育
　　学士 （1995年） 安徽工程科技学院
　　硕士 （2003年） 安徽师范大学
　　博士 （2007年） 安徽师范大学
　　
　　职称职位
　　1995年-2000年 芜湖永康食品厂助理工程师
　　2003年-现在 安徽师范大学 讲师 副教授 硕士生导师
　　2007年-2009年 台湾中兴大学化学系博士后研究员
　　
　　主持项目
　　外消旋稀土金属有机配合物的控制性合成及其催化烯烃可控聚合研究，国家自然科学基金( 20802001)，2009-2011，项目主持人。
　　氮原子配位促进稀土金属-氮键均裂反应研究，安徽省高校青年教师资助计划（2004jq120），项目主持人，已结题。
　　新型含杂原子取代硅桥联茚基稀土配合物的合成及其催化活性研究，安徽省教育厅自然科学基金项目（2005kj331zc），项目主持人，已结题。
　　新型硅桥联茚基稀土配合物的合成及其催化活性研究，安徽师范大学青年基金（2005xqn14），项目主持人，已结题。
　　外消旋稀土金属有机配合物的控制性合成及其催化烯烃的立体可控聚合研究，安徽师范大学博士启动基金，项目主持人。
　　新型连续稀土金属-氮键断裂/攫氧反应研究，国家自然科学基金(20472001)，主要参加人。
　　钯、铑、镍催化活性丙烯酰基在离子液体中的选择性成环偶联反应研究，国家自然科学基金（20572001），主要参加人。
　　
　　研究领域
　　金属有机化学
　　不对称催化合成
　　
　　讲授课程
　　化工基础
　　非金属材料
　　应化专业实验
　　综合化学实验
　　
　　获奖情况
　　芜湖市首届自然科学优秀学术论文一等奖，2004，第二完成人。
　　
　　发表论文
　　Shuangliu Zhou, Chi-Ren Chen, Han-Mou Gau.* “Highly Enantioselective 3-Furylation of Ketones Using (3-Furyl)titanium Nucleophile” Org. Lett. 2010, 12, 48-51.
　　Shuangliu Zhou, Kuo-Hui Wu, Chien-An Chen, Han-Mou Gau*. “Highly Enantioselective Arylation of Aldehydes and Ketones Using AlArEt2(THF) as Aryl Sources” J. Org. Chem. 2009, 74, 3500-3505.
　　Shuangliu Zhou, Da-Wei Chuang, Shih-Ju Chang, Han-Mou Gau* “Synthesis, Characterization, and Structures of Arylaluminum Reagents and Asymmetric Arylation of Aldehydes Catalyzed by a Titanium Complex of N-Sulfonylated Amino Alcohol” Tetrahedron: Asymmetry 2009, 20, 1407-1412.
　　Deepak B. Biradar, Shuangliu Zhou and Han-Mou Gau*. “Direct Asymmetric Catalytic Thienylaluminum Addition to Ketones: A Concise Approach to the Synthesis of (S)-Tiemonium Iodide” Org. Lett. 2009, 11, 3386-3389.
　　Hsu-Tang Yang, Shuangliu Zhou, Feng-Shuo Chang, Chi-Ren Chen and Han-Mou Gau* “Synthesis, Structures, and Characterizations of [ArTi(O-i-Pr)3]2 and Efficient Room-Temperature Aryl-Aryl Coupling of Aryl Bromides with [ArTi(O-i-Pr)3]2 Catalyzed by the Economic Pd(OAc)2/PCy3 System” Organometallics 2009, 28, 5715-5721.
　　Wan-Ting Shu, Shuangliu Zhou, Han-Mou Gau* “Palladium-Catalyzed Cross-Coupling Reaction of ArAlEt2(THF) with Aryl Bromides” Synthesis, 2009, 4075-4081. (Feature Article)
　　Yun Wei, Zeyan Yu, Shaowu Wang*, Shuangliu Zhou, Gaosheng Yang, Lijun Zhang, Guodong Chen, Huimin Qian, Jiaxi Fan. “Synthesis, Characterization and Catalytic Activity of Organolanthanide(II) Complexes with Heterocyclic-Functionalized Fluorenyl Ligands” J. Organomet. Chem. 2008, 693, 2263-2270.
　　Shao-wu Wang,* Hui-min Qian, Wei Yao, Li-jun Zhang, Shuang-liu Zhou, Gao-sheng Yang., Xian-cui Zhu, Jia-xi Fan, Yu-yu Liu, Guo-dong Chen, Hai-bin Song. “ Synthesis of rare earth metal complexes incorporating amido and enolate mixed ligands: Characterization and reactivity” Polyhedron 2008, 27, 2757-2764.
　　Shuangliu Zhou, Shaowu Wang*, Gaosheng Yang, Qinghai Li, Lijun Zhang, Zijian Yao, Zhangkai Zhou, and Haibin Song. “Synthesis, Structure and Diverse Catalytic Activities of Ethylenebis(indenyl)lanthanide(III) Amides on the N-H, C-H Addition to Carbodiimides and e-Caprolactone Polymerization” Organometallics 2007, 26, 3755-3761.
　　Shuangliu Zhou, Shaowu Wang*, Enhong Sheng, Lijun Zhang, Zeyan Yu, Xiaobing Xi, Guodong Chen, Wei Luo, and Yan Li.“Synthesis, Characterization and Catalytic Activity of Some Neodymium(III) and Ytterbium(II) and Europium(II) Complexes With Pyrrolidinyl- and Piperidinyl-Functionalized Indenyl Ligands” Eur. J. Inorg. Chem. 2007, 1519-1528.
　　Shaowu Wang*, Xinliang Tang, Andres Vega, Jean-Yves Saillard, Shuangliu Zhou, Gaosheng Yang, Wei Yao, and Yun Wei. “Coordination and Reactivity Diversity of N-Piperidineethyl- Functionalized Indenyl Ligands: Synthesis, Structure, Theoretical Calculation, and Catalytic Activity of Organolanthanide Complexes with the Ligands”. Organometallics 2007, 26, 1512-1522.
　　Qinghai Li, Shaowu Wang*, Shuangliu Zhou, Gaosheng Yang, Xiancui Zhu, Yuyu Liu. “Highly Atom Efficient Guanylation of both Aromatic and Secondary Amines Catalyzed by Simple Lanthanide Amides” J. Org. Chem. 2007, 72, 6763-6767.
　　Shaowu Wang*, Shaoyin Wang, Shuangliu Zhou, Gaosheng Yang,; Wei Luo, Nan Hu, Zhihong Zhou, Haibin Song. “Synthesis, characterization, and catalytic activity of divalent organolanthanide complexes with new tetrahydro-2H-pyranyl-functionlized indenyl ligands”. J. Organomet. Chem. 2007, 692, 2099.
　　Shaowu Wang*, Xinliang Tang, Andres Vega, Jean-Yves Saillard, Shuangliu Zhou, Gaosheng Yang, Zixiang Huang. “Experimental and Theoretical Evidence for the First Example of an Organolanthanide(II) Compound Having an Indenyl Ligand Bonded to the Metal through the Benzo Ring in h4 Hapticity”. Organometallics 2006, 25, 2399-2401.
　　Lijun Zhang, Shaowu Wang*, Shuangliu Zhou, Gaosheng Yang, and Enhong Sheng. “Cannizzaro-Type Disproportionation of Aromatic Aldehydes to Amides and Alcohols by Using Either a Stoichiometric Amount or a Catalytic Amount of Lanthanide Compounds” J. Org. Chem. 2006, 71, 3149-3153.
　　Lijun Zhang, Shaowu Wang*, Enhong Sheng and Shuangliu Zhou. “A solvent-free synthesis of a, a￠ -bis(substituted benzylidene) cycloalkanones catalyzed by lanthanide amides [(Me3Si)2N]3Ln(m- Cl)Li(THF)3 under microwave irradiation”, Green Chem., 2005, 7, 683-686.
　　FENG Qi-Qing, ZHOU Shuang-Liu, LI Yi-Mei, WANG Shao-Wu*, SHENG En-Hong, HUANG Zi-Xian. “Synthesis and Crystal Structure of {h5:h1-[(2-Methoxyphenyl)-isopropyl]-indenyl}(di- methoxyethylene)lithium” Chinese J. Struct. Chem. 2005, 24, 1046-1048.
　　Enhong Sheng, Shuangliu Zhou, Shaowu Wang*, Gaosheng Yang, Yongyong Wu, Yan Feng, Lili Mao, and Zixiang Huang. “Homolysis of the Ln-N (Ln = Yb, Eu) Bond: Synthesis, Structure, and Catalytic Activity of Ytterbium(II) and Europium(II) Complexes Having (Dimethylamino)propyl- and (Dimethylamino)ethyl-Functional- ized Indenyl Ligands” Eur. J. Inorg. Chem. 2004, 2923.
　　Kehua Zhang, Wu Zhang, Shaowu Wang*, Enhong Sheng, Gaosheng Yang, Meihua Xie, Shuangliu Zhou, Yan Feng, Lili Mao, and Zixiang Huang, “Homolysis of the Ln-N (Ln = Yb, Eu) bond. Synthesis, structural characterization and catalytic activity of ytterbium(II) and europium(II) complexes with methoxyethyl functionalized indenyl ligands” Dalton Transactions 2004, 1029-1037.
　　XIE, Mei-Hua, LIU, Xin-Yuan, LIU, Li, WU, Yong-Yong, WANG, Shao-Wu*, ZHOU, Shuang-Liu, SHENG, En-Hong, YANG, Gao-Sheng, HUANG, Zi-Xiang, “Synthesis, Structure and Catalytic Activity Comparison of Tris- and Tetracoordinated Lanthanide Amides” Chinese Journal of Chemistry 2004, 22, 678-682.
　　Shaowu Wang*, Shuangliu Zhou, Enhong Sheng, Meihua Xie, Kehua Zhang, Lin Cheng, Yan Feng, Lili Mao, and Zixiang Huang, “Homolysis of the Eu-N Bond. “Synthesis, Structural Characterization, and Catalytic Activity of Novel Europium(II) Complexes” Organometallics, 2003, 22, 3546-3552.
　　Shuangliu Zhou, Shaowu Wang*, Gaosheng Yang, Xinyuan Liu, Enhong Sheng, Kehua Zhang, Lin Cheng, Zixiang Huang. “Synthesis, structure, and catalytic activity of tetracoordinate lanthanide amides [(Me3Si)2N]3Ln(m-Cl)Li(THF)3 (Ln = Nd, Sm, Eu)” Polyhedron, 2003, 22, 1019-1024.
　　Enhong Sheng, Shaowu Wang*, Gaosheng Yang, Shuangliu Zhou, Lin Cheng, Kehua Zhang, Zixiang Huang. “A New Heteroatom Coordination Promoted Homolysis of the Yb-N Bond. Synthesis and Structural Characterization of a New Class of Ytterbium(II) and Ytterbium(III) Complexes with Amido and Indenyl Ligands and Catalytic Activities of Ytterbium(II) Complexes” Organometallics 2003, 22, 684.
　　杨高升, 盛恩宏, 程林, 周双六, 孙益民, 王绍武*, “含茂基稀土金属有机络合物催化剂在有机合成中的应用”, 中国稀土学报, 2002, 20, 97–106.
　　
　　会议报告
　　Shuangliu Zhou and Han-Mou Gau*, “Application of the Aluminum Reagents in Enantioselective Arylation of Aldehydes”, 第五届海峡两岸生物无机与材料研讨会。2008年7月，台南，墙报。
　　周双六，王绍武*，“含哌啶杂环取代茚基稀土金属配合物的合成及其催化活性研究”，第十四届全国金属有机化学学术讨论会。2006年10月，苏州，墙报。
　　周双六，王绍武*，盛恩宏，顾家山，“内配位控制合成外消旋桥联茚基稀土金属有机配合物”，第四届全国有机化学学术讨论会。2005年8月，昆明，墙报。
　　周双六，汤新亮，王绍武*，盛恩宏，“稀土金属氮键-均裂反应研究：二价镱金属有机配合物(C9H5-1-R-3-CH2SiMe2NC4H8)2Yb (R = H, Me)的合成、结构和催化活性研究”，第十三届全国金属有机化学学术讨论会。2004年10月，北京，墙报。
　　周双六，王绍武*，盛恩宏，“新型杂原子配位的稀土金属氮键均裂单电子还原反应研究：含N, N-二甲基丙基茚基稀土金属有机配合物的合成及催化活性研究”，第十二届全国金属有机化学学术讨论会。2002年10月，福州，墙报。
　　Shaowu Wang*, Shuangliu Zhou, Lin Cheng, Gaosheng Yang, Enhong Sheng, and Kehua Zhang, “Synthesis, Structure and Catalytic Activities of Sterically Crowded Tetracoordinate Lanthanide Amides [(Me3Si)3N]3Ln(m-Cl)Li(THF)3×xC7H8 (Ln = Sm, Eu, x = 1; Ln = Dy, Tm, x = 1)”, XXth Internatioanl Conference on Organometallic Chemistry, July 7-12, 2002, Corfu, Greece, Post Presentation.
 

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